Notes
Outline
Atoms, Molecules and Ions
Part II- Formulas, Nomenclature, and Equation Balancing
Types of Compounds
Ionic - Compounds composed of Ions
Cations- Positively charged atoms as a result of losing one or more electrons
Anions- Negatively charged atoms as a result of gaining one or more electrons
Molecular- Compounds composed of neutral molecules
Types of Formulas
Simple (Empirical) Formulas
Molecular Formula
Structural Formula
Simpliest (Empirical)Formulas
Formula whose subscripts represent simpliest whole number ratio of atoms per molecule or mols of elements per mol of compound
Example:
CH2O means that there are twice as many Hydrogen atoms as there are Carbon or Oxygen atoms
Ionic compounds have only simpliest formulas
Molecular Formulas
Formula whose subscripts represent absolute numbers of atoms per molecule of compound or absolute numbers of mols of each element per mol of compound
Examples
C6H12O6 means that a single molecule has 6 atoms of Carbon, 12 atoms of Hydrogen, and 6 atoms of Oxygen
Molecular compounds have molecular and empirical formulas
Structural Formulas
Formula that identifies the way the atoms are connected
Different Methods To Picture Molecules
Examples
T-2.15 Molecular and Structural Formulas
T-2.16 Molecular Models of Molecular Elements
Ions and Ionic Compounds
Metals+Non-metals -àIonic Compounds
Cations + Anions à Ionic Compounds
Total Charge must be zero (total positive and total negative must add up to zero)
T-61  Charges of Some Common Ions Found In Ionic Compounds
Binary And Ternary Compounds
Binary Compound-Compound composed of two elements
Examples- HCl, H2O, NaCl, AlCl3
Ternary Compound- Compound composed of three or more elements
Examples- H2SO4, K2CO3, HClO4
Naming Binary Ionic Compounds From Formula
Name the metal cation using element name
Name the non-metalic anion ending in “ide”
If multi-valent metallic cation involved identify the valence in parenthesis
Examples
Determining The Formula Of A Binary Ionic From the Name
Identify the symbol for metal and non-metal
Identify the oxidation state in parenthesis for each
Determine what multiple of each to get a balance between positive and negative
Multiple will be the subscript
Place the metallic cation element first
Examples
T-2.6 Polyatomic Ions
Naming Ternary Ionic Compounds Using The Formula
Name the metal cation using element name
Name the non-metallic anion
If multi-valent metallic cation involved identify the valence in parenthesis
Examples
Writing the Formula of Ternary Compound Using The Name
Identify the symbol for metal and non-metal
Identify the oxidation state in parenthesis for each
Determine what multiple of each to get a balance between positive and negative
Multiple will be the subscript
Place the metallic cation element first
If more than one polyatomic ion involved enclose the polyatomic ion in parenthesis and place the subscript on the outside.
Examples
T-2.8 Oxoanions and Oxoacids
Naming Molecular Compounds From The Formula
If more than one atom involved in the formula use greek prefixes
Mono = 1
Di = 2
Tri = 3
Tetra = 4
Penta = 5
Hexa = 6
Hepta = 7
Examples
Determining Formulas of Molecular Compounds Using The Name
If no prefix or if prefix is “mono” the subscript will be one understood
If di subscript will be 2
If tri subscript will be 3
If tetra subscript will be 4
Examples
Hydrate Compounds
Hydrates-ionic salts that have water molecules physically locked into the crystal structure
Water called “water of hydration” and is part of composition
Determining the Formula Of A Hydrate From The Name
Write the formula of the anhydrous portion as before
Attach the number of water molecules in the Hydrate to the formula of the anhydrous portion according to the greek prefix used in the name given
Examples
Determining the Name of A Hydrate From The Formula
Name the anhydrous portion as before
Identify the number of waters from the Formula given
Attach the proper prefix to the word Hydrate right after the anhydrous name
Examples