Chapter 13

10/11/99


Click here to start


Table of Contents

Chapter 13

Web Sites For Organic Chemistry

Web Sites for I.R., U.V., And NMR

Web Site for Chapter 13

Electromagnetic Spectrum

Instruments In Organic Chemistry

Beer Lambert Law

Types of Electronic Excitation

Examples of Colored Conjugated Systems

Conjugation Effect

Applications of UV/Visible

InfraRed Absorption Spectroscopy

Modes of Molecular Motion

Types of Vibrational Modes

Prerequisites For IR Absorption

Factors Affecting Frequency of Absorption

Characteristic IR Absorption Frequencies

Applications of IR

Types of NMR

Parts of NMR Instrument (CW)

Nuclear Spin: Origin of nmr Signal

Basis for NMR Signal Generation

Information Gathered From Proton NMR signals

Chemical Shift

TetraMethylSilane (TMS)

Factors Affecting Chemical Shift

Electronic Shielding of Protons

Electronic Deshielding of Protons

Sigma Bonding and Lone Pair Electrons: Shielding of Protons

Inductive Effect: Deshielding of Nucleii

Effect of Pi Electrons on Chemical Shift

Chemical Shift:Equivalent and Non-Equivalent Protons

Homotopic protons

Enantiotopic Protons

Diastereotopic Protons

Characteristic Chemical Shifts of Functional Groups

Signal Peak Area

Signal Splitting:Spin Spin Coupling

NMR Spectral Examples

Flourine-19 NMR

Deuterium

Rate Processes And NMR Spectra

Ethyl Bromide Conformers

Cyclohexane Conformers

Ethanol Spectra (Spectrograde)

Ethanol (tech grade)

Carbon 13 NMR

C-13 Chemical Shift

C-13 NMR Splitting

Example C-13 NMR Spectra

Applications of Nuclear Magnetic Resonance

Magnetic Resonance Imaging (MRI)-Advantages Over X-Ray

Principle of MRI

Author: Ralph Logan Jr.

Email: RHL7460@dcccd.edu

Home Page: http://edie.cprost.sfu.ca/~rhlogan

Download presentation source