Chapter 16

10/11/99


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Table of Contents

Chapter 16

Web Site for Chapter 16

Introduction To Acyl Families

Nomenclature of Aldehydes

Carbaldehyde Branch

Alkanoyl Branches

Nomenclature of Ketones

Physical Properties

Synthesis of Aldehydes

Mild Oxidation of Primary Alcohols

Reduction of Acyl Chlorides Using LiAl(t-Butoxy)3H

Reduction of Nitrile or Ester Using Diisobutyl LiAlH

Synthesis of Ketones

Ozonolysis of Alkenes

Friedel Crafts Acylation of Benzene

Oxidation of Secondary Alcohols

Hydration of Alkynes

Lithium Dialkyl Cuprate Treatment on Acyl Halide

Grignard or Organo Lithium Treatment of Nitrile

Nucleophilic Reactions With Carbonyl Compounds

Nucleophilic Addition To A Carbonyl

Hydrolysis of Aldehydes and Ketones

Partial Alcoholysis of Aldehydes and Ketones

Complete Alcoholysis of Aldehydes and Ketones

Partial Thiolysis of Aldehydes and Ketones

Complete Thiolysis of Aldehydes and Ketones

Reactions of Aldehydes and Ketones With Hydrazine

Hydroxylamine Reaction With Aldehydes and Ketones

Semicarbazone Derivatives

Reactions of Aldehydes and Ketones With Phenylhydrazine

Reactions Involving Aldehydes and Ketones

Addition of HCN

Reactions Involving Cyano Hydrins

Hydrolysis of Nitrile Using HCl

Reduction of Cyanohydrins followed by Hydrolysis

Hydrolysis of Cyano Group and Dehydration of Hydroxyl Group

Bisulfite Addition To Aldehydes and Ketones

Addition of Organometallic Reagents to Aldehydes and Ketones

Reformanski Reaction:OrganoZinc Reagent

Oxidation of Aldehydes and Ketones

Hot Basic Potassium Permanganate of Aldehydes

Basic Silver Oxide Treatment of Aldehydes

Baeyer Villiger Oxidation (Omit)

Simple Chemical Tests for Aldehydes

2,4-D Derivative

Tollens Test

Benedict’s Test for Aldehydes

Fehlings Test for Aldehydes

Spectroscopic Properties of Aldehydes and Ketones

Author: Ralph Logan Jr.

Email: RHL7460@dcccd.edu

Home Page: http://edie.cprost.sfu.ca/~rhlogan

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