Chapter 6

10/11/99


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Table of Contents

Chapter 6

Web Site for Chapter 6

Alkyl Halide Family (R-X)

Nucleophilic Substitutions:Net Reaction

Nucleophiles

Leaving Groups

Nucleophilic Substitutions

Kinetics- SN2

Reaction Mechanism-SN2

Transition State Theory

Stereochemistry-SN2

Reaction Kinetics-SN1

Reaction of t-ButylChloride with Hydroxide ion-SN1

Reaction Mechanism-SN1

Carbocation Intermediates-SN1

Stereochemistry-SN1

Solvolysis-SN1

Factors Affecting Rates of SN1 and SN2 Reactions

Substituent Factor-SN2

Substituent Effect-SN1

Concentration of Nucleophile-SN2

Concentration Effect of Nucleophile-SN1

Nucleophilic Strength-SN2

Nucleophilic Strength-SN1

Solvent Effect-SN2

Solvent Effect-SN1

Leaving Group Ability (LGA)- SN2

Leaving Group Ability(LGA)-SN1

Molecular Rearrangement-SN1

Summary-SN1 vs SN2

Organic Synthesis:Functional Group Transformation-SN2

Phenyl and Vinylic Halides

Elimination Reactions of Alkyl Halides-Dehydrohalogenation

Dehydrohalogenation (1,2 elemination)

Bases Used In Dehydrohalogenation

Elimination Mechanisms

E2 Reaction Mechanism

Elimination-E1

Favorable Conditions-E2

Favorable Conditions-E1

SN vs E Reactions

Author: Ralph Logan Jr.

Email: RHL7460@dcccd.edu

Home Page: http://edie.cprost.sfu.ca/~rhlogan

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